Bis(N-isopropyl-N-methyldithiocarbamato-κ2 S,S′)diphenyltin(IV)
نویسندگان
چکیده
The dithio-carbamate anions in the title compound, [Sn(C(6)H(5))(2)(C(5)H(10)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis.
منابع مشابه
Bis(N-ethyl-N-methyldithiocarbamato-κ2 S,S′)diphenyltin(IV)
The dithio-carbamate anions in the title compound, [Sn(C(6)H(5))(2)(C(4)H(8)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis.
متن کاملBis(N-isopropyl-N-methyldithiocarbamato-κ2 S,S′)(1,10-phenanthroline-κ2 N,N′)zinc
The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa-hedral N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H⋯S, C-H⋯π(ZnS(2)C) and π-π [ring centroid distance between centrosymmetri...
متن کاملDi-tert-butylbis(N-isopropyl-N-methyldithiocarbamato-κ2 S,S′)tin(IV)
The dithio-carbamate anions in the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis. The crystal studied was a non-merohedral twin, the ratio of the twin components being 0.82 (1):0.18 (1).
متن کاملBis(μ-N-benzyl-N-methyldithiocarbamato)-1:2κ3 S,S′:S′;1:2κ3 S:S,S′-bis[bis(N-benzyl-N-methyldithiocarbamato-κ2 S,S′)thallium(III)]
The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into ch...
متن کامل(2,2′-Bipyridine-κ2 N,N′)bis(N-ethyl-N-methyldithiocarbamato-κ2 S,S′)zinc(II)
The complete mol-ecule of the title compound, [Zn(C(4)H(8)NS(2))(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C-C bond of the 2,2'-bipyridine mol-ecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010